Isolable zirconium hydride species in the reaction of amido complexes with amine-boranes.
نویسندگان
چکیده
Mono-, di- and trinuclear zirconium hydride species have been isolated in the treatment of amido complexes [Zr(η5-C5Me5)(NMe2)nCl3-n] (n = 3, 1) with amine-borane adducts NHR2BH3 (R2 = Me2, HtBu). The reactions involve the formation of amidoborane ligands with ZrH-B interactions which readily undergo β-hydride elimination to give hydride functions.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 46 16 شماره
صفحات -
تاریخ انتشار 2017